SAFETY DATA SHEET Eucalyptus Lemon Iron Bark Oil
Version: 1.1 Issued: 21st May 2018
Native Oils Australia ABN 68 154 612 487
HAZARDOUS ACCORDING TO WORKSAFE CRITERIA
SECTION 1 – MATERIAL & SUPPLY COMPANY IDENTIFICATION
1.1 Product Identifiers
Product Name: EUCALYPTUS LEMON IRON BARK OIL
CAS No.: 91771-61-6
EINECS: 294-963-6
1.2 Relevant identified uses of the substance or mixture
No further relevant information available Application of the substance / preparation: Perfumes & cosmetics
1.3 Manufacturer / Supplier Details
Supplier: Native Oils Australia
ABN: 68 154 612 487
Address: Unit 2, 1-3 Sommerville Circuit, Emu Plains, NSW Australia 2774
Telephone: 02 4735 5379
1.4 Information in case of emergency
Emergency Telephone: 0408 962 892 (Office Hours 9.00am – 5.00pm Mon-Fri)
Email: info@nativeoilsaustralia.com.au
SECTION 2 – HAZARDOUS IDENTIFICATION
2.1 Classification of the substance / preparation
Classification according to Regulation (EC) No. 1272/2008
Physical Hazards: FL 3
Health Hazards: AT 1; SCI 2; SS 1
Environmental Hazards: EH-A 1, EH-C 1
2.2 Label Elements
Labeling according to Regulation (EC) No. 1272/2008
GHS Signal Word
DANGER
Hazard Statements
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H410 Very toxic to aquatic life with long lasting effects
Precautionary Statements
P273 Avoid release into the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a Poisons Centre or doctor/physician.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
Lenses if present and continue rinsing
P332 + P313 If skin irritation occurs seek medical advice
P501 Dispose of contents/the container in accordance with local government regulations
2.3 Other hazards
May cause skin irritation/allergy. Patch test recommended
SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Chemical Identification
Description: Eucalyptus staigeriana
CAS No.: 91771-61-6
EINECS No.: 294-963-6
3.2 Chemical constituents
Chemical Name CAS No. EINECS Regulation (EC) No 1272/2008 Limit
1,8-cineole 5989-27-5 227-813-5 FL3, H226; AT 1, H304 SC/I 2, H315; ED/I 1, H318SS 1, H317 ≤ 6.0 %
Citral 5392-40-5 227-813-5 AT 5, H303; SC/I 2, H315; ED/I 1, H318; SS 1, H317 ≤ 38.0 %
Terpinolene 586-62-9 209-578-0 FL 3, H226; AT 5, H303 SCI 2A, H315; SS 1, H317 EH-A 1, EH-C 1, H410 ≤ 10.0 %
Geraniol 99-83-2 202-792-5 FL 3, H226; AT 1, H304 SS 1, H317 ≤ 6.5 %
Geranyl acetate 127-91-3 204-872-5 FL 3, H226; AT 1, H304 SS 1, H317 EH-A 1, EH-C 1, H410 ≤ 3.5
SECTION 4 – FIRST AID
4.1 Description of first aid measures
Eye Contact: Check for and remove any contact lenses. Immediately wash thoroughly with soft, clean water for 15
minutes while holding the eyelids open. Cold water may be used. If symptoms persist, seek medical
attention.
Skin Contact: Remove any contaminated clothing and footwear. Clean before re-use.
Wash affected areas thoroughly with soap and water for at least 15 minutes. In the event of an allergic
reaction, seek medical attention
Inhalation: Remove individual from the exposure to fresh air. Contact a physician as necessary.
Ingestion: Not an expected route of exposure. If swallowed, DO NOT induce vomiting. Wash out mouth with water.
Contact a physician or local poison centre immediately.
Contact Point: Poisons Information Centre Sydney Telephone: 131126
4.2 Most important symptoms and effects of substance, both acute and delayed
Eye contact: May cause eye irritation and corneal damage if not immediately rinsed out.
Skin Contact: Repeated contact may cause allergic dermatitis
Inhalation: Remove subject and place in a fresh air environment
Ingestion: Not an expected route of exposure
4.3 Indication of immediate medical attention and any special treatment required
No further relevant information available
SECTION 5 – FIRE FIGHTING MEASURES
5.1 Extinguishing Media
Suitable extinguishing agents: Carbon Dioxide; Dry Chemical; Water spray; Alcohol-resistant foam.
Unsuitable Extinguishing Media: Water jet (Use of a water jet may cause the fire to spread)
5.2 Special hazards arising from the substance or mixture
None known
5.3 Advice for firefighters
Use self-contained breathing apparatus and wear protective clothing
Additional information
Collect contaminated firefighting water separately to prevent from entering waterways.
Contact Point: Dial 000 Emergency in case of fire [In Australia] or Local Emergency Authority [Out of Australia].
SECTION 6 – ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all sources of ignition.
Ventilate area. Do not smoke.
6.2 Environmental precautions
Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer
system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
6.3 Methods and materials for containment and cleaning up
Wipe up small spills with absorbent material such as paper cloth. Cover larger spills with sand, earth or other
noncombustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and
transfer to properly labeled containers. Take precautionary measures against static discharges. Keep away from ignition
sources, do not smoke and avoid flames. Dispose of contaminated material in accordance with local government
regulations
6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment
See Section 13 for disposal information
SECTION 7 – HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin, eyes and avoid inhalation. Use glasses and protective gloves. Ensure there is adequate ventilation.
Do not smoke. Take necessary action to avoid static discharge (which might cause ignition of organic vapors).
7.2 Conditions for storage
Keep container tightly closed in a dry and well-ventilated place. Keep out of reach of children. Keep away from heat and
sources of ignition. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers.
Keep away from heat.
Incompatible products None known based on information supplied.
7.3 Specific end use No further information available
SECTION 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Control parameters. Not regulated
8.2 Exposure Controls
Respiratory Protection Not generally required in well ventilated workplace. Ventilation Protection Ensure adequate ventilation to keep exposure levels to a minimum. General exhaust is
recommended
Eye Protection Use of goggles is recommended
Protective Gloves Use of chemical resistant (nitrile) gloves is recommended
Protective Clothing Use of chemical resistant clothing is recommended
Protective Equipment An eyewash station should be made available
8.3 Special Engineering Controls
None established.
8.4 Other Personal Protection
Consult the following Australian Standards for general advice regarding safety clothing and equipment: Respiratory
Equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS 2919, Industrial Eye Protection: AS 1336
and AS/NZS 1337, Occupational Protective Footwear: AS/NZS 2210.
Note
These precautions are for room temperature handling. Use at elevated temperature
applications may require additional precautions.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
9.1 General information
Physical appearance at 20°C: Clear mobile liquid
Colour: Colourless to pale yellow
Odour: Characteristic, woody citrus
pH when measurable: Not available
Melting point & Freezing point: N.A.
Initial boiling point: N.A.
Flash point: 41°C
Flammability (solid, gas): N.A.
Upper & lower flammability or explosive limits: N.A.
Vapour pressure: N.A.
Vapour Density (air = 1): N.A.
Relative density at 20°C: 0.871 to 0.893
Solubility in water (g/litre @ 20 °C): Insoluble
Solubility in ethanol: Soluble
Auto ignition T°C: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: Lower & Upper Limits: N.A.
Explosion hazards: No risk at room temperature, comply with current
legislation requirements
Combustion Properties: Does not contain any substance known as to ignite spontaneously.
9.2 Other Data
Refractive index at 20 °C: 1.480 to 1.510
Optical rotation at 20°C: -38.0° to -20.0°
Main Constituents: Citral (20 to 38%)
β-phellandrene (12.0 to 38.0%)
SECTION 10 – STABILITY AND REACTIVITY
10.1 Reactivity
This material presents no significant reactivity hazard and is stable to shock, vibration and pressure under normal
conditions of use. In the presence of light and heat, there may be oxidation.
10.2 Stability
Chemically stable material under the recommended storage and handling conditions in Section 7
10.3 Possibility of hazardous reactions
When exposed to high temperatures, the substance may release hazardous decomposition products such as carbon
monoxide, carbon dioxide, fumes, and nitrogen oxide
10.4 Conditions to avoid
Do not heat above 41°C. Do not expose containers to the sun.
10.5 Incompatible materials
Strong oxidising agents
10.6 Hazardous decomposition products
No dangerous decomposition products expected by intended use
SECTION 11 – TOXICOLOGICAL INFORMATION
11.1 Substance Acute toxicity
No data available.
Skin corrosion/irritation
May cause an allergic skin reaction. See Section 3.
Serious eye damage/irritation
No significant effects or critical hazards
Carcinogenicity
No significant effects or critical hazards
Germ cell mutagenicity
No significant effects or critical hazards
Reproductive toxicity
No significant effects or critical hazards
STOT-single exposure
Not specified
STOT-related exposure
Not specified
Aspiration hazard
May be fatal if swallowed and enters airways.
11.2 Information on the likely routes of exposure
Skin/scalp contact.
11.3 Symptoms related to the physical, chemical, and toxicological characteristics
None known. Irritation of the eye if exposed
SECTION 12 – ECOLOGICAL INFORMATION
12.1 Ecotoxicity
Very toxic to aquatic life with long term effects.
12.2 Persistence and degradability
Data not available
12.3 Bio-accumulative potential
Data not available
12.4 Mobility in soil
Data not available
12.5 Other adverse effects
Avoid exposure to marine environments and waterways
SECTION 13 – DISPOSAL CONSIDERATIONS
13.1 Waste Material
Do not pour into drains or waterways. Waste management to be carried out without risk to water, air, soil, plants or
animals. Place waste material into sealed containers and dispose of in accordance with current applicable laws and
regulations.
13.2 Contaminated Packaging
Recycle where possible and dispose of empty containers in accordance with current local government regulations.
SECTION 14 – TRANSPORT INFORMATION
14.1 UN Number
1169
14.2 UN Proper shipping name
Extracts, aromatic, liquid
14.3 Transportation hazard classes
Road and Rail Transport:
Classified as Dangerous Goods according to the criteria of the Australian Dangerous Goods Code (ADG Code) for
transport by Road and Rail.
Marine Transport:
Classified as Dangerous Goods according to the criteria of the ADG Code for transport by sea.
Air Transport:
Classified as hazardous by the criteria of the International Air Transport Association as
(IATA) Dangerous Goods Regulations for transport by air.
14.4 Packing group
III
14.5 Environmental hazards
14.6 Poison Schedule
Not scheduled as a poison
14.7 Hazchem Code
Not regulated
SECTION 15 – REGULATORY INFORMATION
15.1 EU regulations
This product has been classified and marked in accordance with the EU Directives/Ordinance on Hazardous Materials.
15.2 Poisons Schedule (Aust): Listed as a Poison by the SUSDP.
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS). This material in
neither hazardous nor dangerous.
SECTION 16 – OTHER INFORMATION
The information contained in this Safety Data Sheet is obtained from current and reliable sources. Native Oils Australia provides the
information contained herein in good faith but makes no representation as to
its comprehensiveness or accuracy. This Safety Data Sheet summarises our best current knowledge of the
health and safety hazard information of the product but does not claim to be all inclusive. This document is thus,
intended only as a guide to the appropriate precautionary handling of the material by properly trained personnel using
this product. Individuals receiving this information must exercise their independent judgment in determining its
appropriateness for the specific purpose. As the ordinary or otherwise use(s) of this product is outside the control of
Native Oils Australia., no representation or warranty, expressed or implied, is made as to the effect(s) of
such use(s), (including damage or injury), or the results obtained. Native Oils Australia expressly
disclaims responsibility as to the ordinary or otherwise use(s). Furthermore, nothing contained herein should be
considered as a recommendation by Native Oils Australia as to the fitness for any use. The liability of
Native Oils Australia is limited to the value of the goods and does not include any consequential loss.
Native Oils Australia shall not be liable for any errors or delays in the content, or for any actions taken in
reliance thereon. Native Oils Australia shall not be responsible for any damages resulting from use of or
reliance upon this information. The user of the product is solely responsible for compliance with all laws and
regulations applying to the use of the products, including intellectual property rights of third parties.
Manufacturers Statement:
Essential oils are complex, naturally derived chemicals. Often the constituents of the EOs may individually have known risks and
hazards, and in some cases the constituents have not been studied, often because there have been no complaints.
Used as directed and within the limits specified by the various agencies and associations that study these materials, essential oils
are safe and useful ingredients in flavours, fragrances, cosmetics and therapeutic applications. Please refer to the guidelines of the
industry in which the product will be offered to the public to abide by the safest known practices. Those organizations include: IFRA,
IFEAT, AHPA, ISO Standards for Essential Oils, and publications by various government health organizations regarding the use of
these materials.